Matches in SemOpenAlex for { <https://semopenalex.org/work/W2040748030> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W2040748030 endingPage "1787" @default.
- W2040748030 startingPage "1776" @default.
- W2040748030 abstract "The symmetric four-armed geometry of pentaerythrityl tetraphenyl ether (5) makes it a valuable starting point for building complex molecular and supramolecular structures. In particular, it provides a core to which multiple sites of attractive intermolecular interaction can be attached, thereby creating compounds predisposed to form complex networks by association. To facilitate exploitation of the pentaerythrityl tetraphenyl ether core in such ways, we have prepared more than 20 new derivatives by efficient methods. Of special interest are compounds 3 and 4, which incorporate four diaminotriazine groups attached to the meta and para positions of the pentaerythrityl tetraphenyl ether core. Crystallization of compounds 3 and 4 from DMSO/dioxane is directed by hydrogen bonding of the diaminotriazine groups according to well-established motifs, thereby producing three-dimensional networks. In forming these networks, each molecule of compound 3 forms a total of 12 hydrogen bonds with six others, whereas each molecule of compound 4 forms a total of 16 hydrogen bonds with four others. Both networks are highly porous and define significant interconnected channels for the inclusion of guests. In crystals of compounds 3 and 4, the fraction of the volume accessible to guests is 66% and 57%, respectively. In both cases, the pentaerythrityl tetraphenyl ether cores adopt conformations that deviate substantially from tetrahedral geometry. It is noteworthy that the inherent flexibility of the core does not favor the formation of close-packed guest-free structures." @default.
- W2040748030 created "2016-06-24" @default.
- W2040748030 creator A5030572816 @default.
- W2040748030 creator A5058097206 @default.
- W2040748030 creator A5079440576 @default.
- W2040748030 date "2004-02-14" @default.
- W2040748030 modified "2023-10-12" @default.
- W2040748030 title "Molecular Tectonics. Porous Hydrogen-Bonded Networks Built from Derivatives of Pentaerythrityl Tetraphenyl Ether" @default.
- W2040748030 cites W1967291155 @default.
- W2040748030 cites W1969260867 @default.
- W2040748030 cites W1980321194 @default.
- W2040748030 cites W1982171854 @default.
- W2040748030 cites W1985189845 @default.
- W2040748030 cites W1998197988 @default.
- W2040748030 cites W2000222205 @default.
- W2040748030 cites W2002931650 @default.
- W2040748030 cites W2007860556 @default.
- W2040748030 cites W2010717776 @default.
- W2040748030 cites W2015668512 @default.
- W2040748030 cites W2019663466 @default.
- W2040748030 cites W2031736116 @default.
- W2040748030 cites W2031916620 @default.
- W2040748030 cites W2040177609 @default.
- W2040748030 cites W2047540964 @default.
- W2040748030 cites W2060863556 @default.
- W2040748030 cites W2069075655 @default.
- W2040748030 cites W2071602352 @default.
- W2040748030 cites W2071903132 @default.
- W2040748030 cites W2075177835 @default.
- W2040748030 cites W2107297909 @default.
- W2040748030 cites W2119058025 @default.
- W2040748030 cites W2147252225 @default.
- W2040748030 cites W2147304506 @default.
- W2040748030 cites W2168387749 @default.
- W2040748030 cites W2169708356 @default.
- W2040748030 cites W2949658557 @default.
- W2040748030 cites W96955890 @default.
- W2040748030 doi "https://doi.org/10.1021/jo035311h" @default.
- W2040748030 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15058918" @default.
- W2040748030 hasPublicationYear "2004" @default.
- W2040748030 type Work @default.
- W2040748030 sameAs 2040748030 @default.
- W2040748030 citedByCount "87" @default.
- W2040748030 countsByYear W20407480302012 @default.
- W2040748030 countsByYear W20407480302013 @default.
- W2040748030 countsByYear W20407480302014 @default.
- W2040748030 countsByYear W20407480302015 @default.
- W2040748030 countsByYear W20407480302016 @default.
- W2040748030 countsByYear W20407480302017 @default.
- W2040748030 countsByYear W20407480302018 @default.
- W2040748030 countsByYear W20407480302019 @default.
- W2040748030 countsByYear W20407480302020 @default.
- W2040748030 countsByYear W20407480302021 @default.
- W2040748030 countsByYear W20407480302022 @default.
- W2040748030 countsByYear W20407480302023 @default.
- W2040748030 crossrefType "journal-article" @default.
- W2040748030 hasAuthorship W2040748030A5030572816 @default.
- W2040748030 hasAuthorship W2040748030A5058097206 @default.
- W2040748030 hasAuthorship W2040748030A5079440576 @default.
- W2040748030 hasConcept C112887158 @default.
- W2040748030 hasConcept C166950319 @default.
- W2040748030 hasConcept C178790620 @default.
- W2040748030 hasConcept C185592680 @default.
- W2040748030 hasConcept C203036418 @default.
- W2040748030 hasConcept C2780407432 @default.
- W2040748030 hasConcept C32909587 @default.
- W2040748030 hasConcept C8010536 @default.
- W2040748030 hasConcept C93275456 @default.
- W2040748030 hasConceptScore W2040748030C112887158 @default.
- W2040748030 hasConceptScore W2040748030C166950319 @default.
- W2040748030 hasConceptScore W2040748030C178790620 @default.
- W2040748030 hasConceptScore W2040748030C185592680 @default.
- W2040748030 hasConceptScore W2040748030C203036418 @default.
- W2040748030 hasConceptScore W2040748030C2780407432 @default.
- W2040748030 hasConceptScore W2040748030C32909587 @default.
- W2040748030 hasConceptScore W2040748030C8010536 @default.
- W2040748030 hasConceptScore W2040748030C93275456 @default.
- W2040748030 hasIssue "6" @default.
- W2040748030 hasLocation W20407480301 @default.
- W2040748030 hasLocation W20407480302 @default.
- W2040748030 hasOpenAccess W2040748030 @default.
- W2040748030 hasPrimaryLocation W20407480301 @default.
- W2040748030 hasRelatedWork W1580507190 @default.
- W2040748030 hasRelatedWork W1974821220 @default.
- W2040748030 hasRelatedWork W2023799671 @default.
- W2040748030 hasRelatedWork W2030574793 @default.
- W2040748030 hasRelatedWork W2131677795 @default.
- W2040748030 hasRelatedWork W2137366329 @default.
- W2040748030 hasRelatedWork W2142401223 @default.
- W2040748030 hasRelatedWork W2340553995 @default.
- W2040748030 hasRelatedWork W2801420880 @default.
- W2040748030 hasRelatedWork W3211156424 @default.
- W2040748030 hasVolume "69" @default.
- W2040748030 isParatext "false" @default.
- W2040748030 isRetracted "false" @default.
- W2040748030 magId "2040748030" @default.
- W2040748030 workType "article" @default.