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- W2040773663 abstract "Two highly hydrophobic Lewis X glycolipids 2 and 3 were prepared. The glycoconjugate 2 was constructed in the following way: pentaerythrytol was used as a distributor on which three racemic phytol hydrophobic chains and a triethyleneglycol spacer β-glycosylated with the pentasaccharide Gal (β 1−4)[Fuc (α 1−3)] GlcNAc (β 1−3) Gal (β 1−4) Glc were anchored. The glycoconjugate 3 was constructed in a similar way, the sugar moiety being the trisaccharide Gal (β 1−4)[Fuc (α 1−3)] GlcNAc, the so-called Lewis X determinant. A triethyleneglycol spacer was used in order to introduce the mobility required for the study of single carbohydrate−carbohydrate interactions. Three phytyl chains increase the hydrophobicity of the lipid moiety compared to the natural ceramide glycolipid 1. These glycolipids display a liquid-expanded behaviour with a high compressibility in monolayer studies. These properties associated with a low solubility in water make them good candidates for the study of the interaction between two Lewis X functionalized vesicles." @default.
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- W2040773663 date "2001-01-01" @default.
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- W2040773663 title "New Highly Hydrophobic Lewis X Glycolipids: Synthesis and Monolayer Behaviour" @default.
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- W2040773663 doi "https://doi.org/10.1002/1099-0690(200101)2001:2<253::aid-ejoc253>3.0.co;2-2" @default.
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