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- W2040777595 abstract "The hydrogen atom abstraction reaction of C3H+ with H2 is shown by gas-phase ion—molecule bracketing reactions to be exothermic, with a small (about 1 kcal mol−1 barrier. The heats of formation of the cyclic and linear isomers of C3H+2 are determined to be 322 ± 4 kcal mol−1 and 334 ± 4 kcal mol−1 respectively. Ab initio calculations confirm that the cyclic isomer is the more stable form by 12 kcal mol−1. The results are compared with the thermochemistry determined by other workers." @default.
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- W2040777595 date "1990-10-01" @default.
- W2040777595 modified "2023-10-14" @default.
- W2040777595 title "The heats of formation of cyclic and linear C3H+2" @default.
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- W2040777595 doi "https://doi.org/10.1016/0168-1176(90)85103-9" @default.
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