Matches in SemOpenAlex for { <https://semopenalex.org/work/W2040778698> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W2040778698 endingPage "162" @default.
- W2040778698 startingPage "158" @default.
- W2040778698 abstract "In the field of solid-state chemical hydrogen storage, ammonia borane NH3BH3 has been widely studied while hydrazine borane N2H4BH3 can be considered as a “novel” material. In the present work, we investigated the behaviour of these boranes when mixed together in a mole ratio of 1:1. Hydrazine borane and ammonia borane destabilize each other. Though stable at 20–25 °C, the mixture melts at ∼30 °C and then undergoes significant decomposition, with desorption of hydrogen H2 and hydrazine N2H4 from 67 °C. This is explained by the fact that the presence of hydrazine borane disrupts the Hδ+⋯Hδ− network of ammonia borane, and vice versa; the mixture is then much less stable than the pristine boranes. The mixture can nevertheless be stabilized (by heat- or vacuum-treatment and thus extraction of evolving hydrogen and hydrazine), making the as-obtained solid a potential chemical hydrogen storage material. Over the range 25–300 °C, it is able to release ca. 11.4 wt% of almost pure H2. Furthermore forms boron nitride as the solid residue, at temperatures as low as 300 °C." @default.
- W2040778698 created "2016-06-24" @default.
- W2040778698 creator A5020174691 @default.
- W2040778698 creator A5020973449 @default.
- W2040778698 creator A5035087361 @default.
- W2040778698 creator A5035420812 @default.
- W2040778698 creator A5067485157 @default.
- W2040778698 creator A5088378118 @default.
- W2040778698 date "2014-08-01" @default.
- W2040778698 modified "2023-09-25" @default.
- W2040778698 title "Hydrazine borane-induced destabilization of ammonia borane, and vice versa" @default.
- W2040778698 cites W1578586225 @default.
- W2040778698 cites W1975724631 @default.
- W2040778698 cites W1978331189 @default.
- W2040778698 cites W1994799047 @default.
- W2040778698 cites W2000884299 @default.
- W2040778698 cites W2006547129 @default.
- W2040778698 cites W2008676909 @default.
- W2040778698 cites W2017898047 @default.
- W2040778698 cites W2018032554 @default.
- W2040778698 cites W2111217908 @default.
- W2040778698 cites W2113441894 @default.
- W2040778698 cites W2136546330 @default.
- W2040778698 cites W2163355076 @default.
- W2040778698 cites W2314013358 @default.
- W2040778698 cites W2320854343 @default.
- W2040778698 doi "https://doi.org/10.1016/j.jhazmat.2014.05.082" @default.
- W2040778698 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24956580" @default.
- W2040778698 hasPublicationYear "2014" @default.
- W2040778698 type Work @default.
- W2040778698 sameAs 2040778698 @default.
- W2040778698 citedByCount "9" @default.
- W2040778698 countsByYear W20407786982015 @default.
- W2040778698 countsByYear W20407786982017 @default.
- W2040778698 countsByYear W20407786982018 @default.
- W2040778698 countsByYear W20407786982019 @default.
- W2040778698 countsByYear W20407786982020 @default.
- W2040778698 countsByYear W20407786982023 @default.
- W2040778698 crossrefType "journal-article" @default.
- W2040778698 hasAuthorship W2040778698A5020174691 @default.
- W2040778698 hasAuthorship W2040778698A5020973449 @default.
- W2040778698 hasAuthorship W2040778698A5035087361 @default.
- W2040778698 hasAuthorship W2040778698A5035420812 @default.
- W2040778698 hasAuthorship W2040778698A5067485157 @default.
- W2040778698 hasAuthorship W2040778698A5088378118 @default.
- W2040778698 hasConcept C124681953 @default.
- W2040778698 hasConcept C161790260 @default.
- W2040778698 hasConcept C178790620 @default.
- W2040778698 hasConcept C179104552 @default.
- W2040778698 hasConcept C185592680 @default.
- W2040778698 hasConcept C2776382133 @default.
- W2040778698 hasConcept C2776597398 @default.
- W2040778698 hasConcept C2778470625 @default.
- W2040778698 hasConcept C2778553741 @default.
- W2040778698 hasConcept C2778826510 @default.
- W2040778698 hasConcept C43617362 @default.
- W2040778698 hasConcept C501308230 @default.
- W2040778698 hasConcept C512968161 @default.
- W2040778698 hasConcept C68044625 @default.
- W2040778698 hasConceptScore W2040778698C124681953 @default.
- W2040778698 hasConceptScore W2040778698C161790260 @default.
- W2040778698 hasConceptScore W2040778698C178790620 @default.
- W2040778698 hasConceptScore W2040778698C179104552 @default.
- W2040778698 hasConceptScore W2040778698C185592680 @default.
- W2040778698 hasConceptScore W2040778698C2776382133 @default.
- W2040778698 hasConceptScore W2040778698C2776597398 @default.
- W2040778698 hasConceptScore W2040778698C2778470625 @default.
- W2040778698 hasConceptScore W2040778698C2778553741 @default.
- W2040778698 hasConceptScore W2040778698C2778826510 @default.
- W2040778698 hasConceptScore W2040778698C43617362 @default.
- W2040778698 hasConceptScore W2040778698C501308230 @default.
- W2040778698 hasConceptScore W2040778698C512968161 @default.
- W2040778698 hasConceptScore W2040778698C68044625 @default.
- W2040778698 hasLocation W20407786981 @default.
- W2040778698 hasLocation W20407786982 @default.
- W2040778698 hasLocation W20407786983 @default.
- W2040778698 hasLocation W20407786984 @default.
- W2040778698 hasOpenAccess W2040778698 @default.
- W2040778698 hasPrimaryLocation W20407786981 @default.
- W2040778698 hasRelatedWork W1971912159 @default.
- W2040778698 hasRelatedWork W2010308674 @default.
- W2040778698 hasRelatedWork W2013123425 @default.
- W2040778698 hasRelatedWork W2040778698 @default.
- W2040778698 hasRelatedWork W2047101768 @default.
- W2040778698 hasRelatedWork W2068047453 @default.
- W2040778698 hasRelatedWork W2955925028 @default.
- W2040778698 hasRelatedWork W3210647393 @default.
- W2040778698 hasRelatedWork W4290074959 @default.
- W2040778698 hasRelatedWork W4292551174 @default.
- W2040778698 hasVolume "278" @default.
- W2040778698 isParatext "false" @default.
- W2040778698 isRetracted "false" @default.
- W2040778698 magId "2040778698" @default.
- W2040778698 workType "article" @default.