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• W2040779825 abstract "The reaction of indenyllithium, IndLi, with CpMCl3 (M  Ti, Zr) or Cp∗MCl3 (M  Zr, Hf) leads to complexes of the type (L)(Ind)MCl2 (1: L  Cp, M  Ti; 2: L  Cp, M  Zr; 3: L  Cp∗, M  Zr; 4: L  Cp∗, M  Hf). In combination with methylaluminoxan (MAO), complexes 1–4 show a high catalytic activity as homogeneous ethylene polymerization catalysts. The ethylene selective catalyst precursor 3 was characterized by an X-ray structure analysis. Die Umsetzung von Indenyllithium, IndLi, mit CpMCl3 (M  Ti, Zr) bzw. Cp∗MCl3 (M  Zr, Hf) führt zu Komplexen des Typs (Ind)(L)MCl2 (1: L  Cp, M  Ti; 2: L  Cp, M  Zr; 3: L  Cp∗, M  Zr; 4: L  Cp∗, M  Hf), die in Verbindung mit Methylaluminoxan (MAO) hochaktive Katalysatoren für die Ethylenpolymerisation darstellen. Von der ethylenselektiven Katalysatorvorstufe 3 liegt eine Molekülstruktur vor." @default.
• W2040779825 created "2016-06-24" @default.
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• W2040779825 date "1996-05-01" @default.
• W2040779825 modified "2023-09-27" @default.
• W2040779825 title "Unverbrückte indenylkomplexe mit metallen der vierten gruppe als katalysatoren bei der homogenen olefinpolymerisation" @default.
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• W2040779825 doi "https://doi.org/10.1016/0022-328x(95)05987-z" @default.
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