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• W2040782829 abstract "We present temperature programmed desorption data and inverse photoemission (IPE) spectra that directly demonstrate the effects of quantum confinement of electrons in an ultrathin metal film on molecular chemisorption at the film's surface. The prototypical system of CO adsorbed on the $n$-monolayers-$mathrm{Cu}∕mathrm{fcc}mathrm{Fe}∕mathrm{Cu}(100)phantom{rule{0.3em}{0ex}}[2<n<15]$ was explored. For all films, the CO peak desorption temperature $({T}_{mathrm{des}})$ is lower than that of Cu(100). Moreover, oscillations in ${T}_{mathrm{des}}$ are correlated with oscillations in the IPE intensity at the Fermi level $({E}_{mathrm{F}})$ caused by metallic quantum well states in the Cu overlayer passing through ${E}_{mathrm{F}}$ as function of film thickness." @default.
• W2040782829 created "2016-06-24" @default.
• W2040782829 creator A5021272879 @default.
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• W2040782829 date "2004-10-28" @default.
• W2040782829 modified "2023-09-26" @default.
• W2040782829 title "Quantum size effect induced modification of the chemisorption properties of thin metal films" @default.
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• W2040782829 doi "https://doi.org/10.1103/physrevb.70.165420" @default.
• W2040782829 hasPublicationYear "2004" @default.
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