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• W2040792110 abstract "In the title compound, [Cu(C 2 N 3 ) 2 (C 12 H 10 N 6 )] n or [Cu(dca) 2 (abpt)] n , where abpt is 4-amino-3,5-bis(pyridin-2-yl)-4 H -1,2,4-triazole and dca is the dicyanamide anion, the Cu II centre is five-coordinate with an approximately square-pyramidal geometry. One of the two dicyanamide ligands is a terminal ligand, but the other one acts as a μ 1,5 -bridging ligand between pairs of Cu II centres, so generating a one-dimensional coordination polymer. A combination of N—H...N and C—H...N hydrogen bonds, augmented by π–π stacking interactions, links the coordination polymer chains into a bilayer structure. Comparisons are made with some related Cu II complexes containing dca ligands and heteroaromatic co-ligands." @default.
• W2040792110 created "2016-06-24" @default.
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• W2040792110 date "2014-03-16" @default.
• W2040792110 modified "2023-09-27" @default.
• W2040792110 title "<i>catena</i>-Poly[[[4-amino-3,5-bis(pyridin-2-yl)-4<i>H</i>-1,2,4-triazole-κ²<i>N</i>¹,<i>N</i>⁵](dicyanamido-κ<i>N</i>)copper(II)]-μ₂-dicyanamido-κ²<i>N</i>:<i>N</i>′]: coordination polymer chains linked into a bilayer by hydrogen bonds and π–π stacking interactions" @default.
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• W2040792110 doi "https://doi.org/10.1107/s205322961400504x" @default.
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