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- W2040792550 abstract "The mixed oxide (Gd1-xYx)2O3 (0.0 ≤ x ≤ 1.0) were synthesized, as powder and thin film, by a sol-gel process. X-ray diffraction data were collected and crystal structure and microstructure analysis were performed using Rietveld refinement method. All samples were found to have the same crystal system and formed solid solutions over the whole range of x. The cationic distribution, Gd3+ and Y3+, over the two non-equivalent sites 8b and 24d of the space group Ia3 is found to be random for all values of (x). The lattice parameter is found to vary linearly with the composition (x). Replacing Gd3+ and Y3+ by each other introduces a systemic decrease in the x-coordinate of cation position (24d) and slight changes in the oxygen coordinates. Crystallite size and microstrain analysis is performed along different crystallographic directions and anisotropic changes are found with the composition parameter (x). The average crystallite size ranges from 75 to 149 nm and the r.m.s strain from 0.027 to 0.068 x10-2. Textured Gd1.841Y0.159O3 (400) buffer layers, with a high degree of alignment in both out-plane and in-plan, are successfully grown on cube textured Ni (001) tape substrates by sol–gel dip coating process. The resulting buffer layers are crack-free, pinhole-free, dense and smooth. YbBa2Cu3O7-x (YbBCO) thin film could be (00l) epitaxially grown on the obtained buffer layer using sol–gel dipping technique. (© 2007 WILEY -VCH Verlag GmbH & Co. KGaA, Weinheim)" @default.
- W2040792550 created "2016-06-24" @default.
- W2040792550 creator A5010993838 @default.
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- W2040792550 date "2008-03-01" @default.
- W2040792550 modified "2023-09-30" @default.
- W2040792550 title "X-ray diffraction analysis of powder and thin film of (Gd1-xYx)2O3 prepared by sol-gel process" @default.
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- W2040792550 doi "https://doi.org/10.1002/crat.200710997" @default.
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