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• W2040803771 abstract "Inelastic electron-transfer kinetics in molecules with electron donor and acceptor units connected by a bridge is expected to be sensitive to bridge-localized vibronic interactions. Here, we show how inelastic electron transfer may be turned on and off in a double-slit style experiment that uses the molecule as an interferometer. We describe donor-acceptor interactions in terms of interfering vibronic coupling pathways that can be actively selected (labeled) when pathway-specific vibrations are excited by infrared radiation. Thus, inelastic tunneling may be actively controlled, and we suggest strategies for building molecular scale quantum interferometers and switches based on this phenomenon." @default.
• W2040803771 created "2016-06-24" @default.
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• W2040803771 date "2009-04-02" @default.
• W2040803771 modified "2023-09-30" @default.
• W2040803771 title "Turning Charge Transfer On and Off in a Molecular Interferometer with Vibronic Pathways" @default.
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• W2040803771 doi "https://doi.org/10.1021/nl8037695" @default.
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