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- W2040804087 abstract "Abstract An approach to the description of molecular interactions in normal- and reversed-phase high-performance liquid chromatography as quasi-chemical equilibria on the sorbent and in solution (of solute—solvent, modifier—sorbent, solute—modifier and modifier—modifier types) is presented. Such an approach is of help in understanding better the role of various parameters of chromatographic systems that determine the retention of substances in HPLC. The mathematical mechanism used is the same to describe the equilibrium distribution of the sorbate between the liquid and solid phases (adsorption mechanism) or between the liquid and bonded phases (absorption mechanism) and the final equations do not take into account the type of mechanism. A general expression correlating the retention of solute molecules with the concentration of the modifying additive of the mobile phase (over a wide range of concentrations) was obtained. Numerous examples have shown that, depending on the prevalence of certain types of interactions, this relationship makes it possible to describe quantitatively and to explain deviations of the retention dependence from linearity." @default.
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- W2040804087 date "1991-01-01" @default.
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- W2040804087 title "Molecular interactions in liquid chromatography" @default.
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