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- W2040806685 abstract "Total and partial cross sections for breakup of the ground rovibronic state of ${mathrm{H}}_{2}^{+}$ by photon impact are calculated using the exact nonadiabatic nonrelativistic Hamiltonian without approximation. The converged results span six orders of magnitude. The breakup cross section is divided into dissociative excitation and dissociative ionization. The dissociative excitation channels are divided into contributions from principal quantum numbers 1--4. For dissociative ionization, the fully differential cross section is calculated using a formally exact expression. These results are compared with approximate expressions. The Born-Oppenheimer expression for the dissociative ionization amplitude is shown to be deficient near onset. A Born-Oppenheimer approximation to the final state is shown to give accurate results for the sharing of kinetic energy between the electronic and the internuclear degrees of freedom---the doubly differential cross section. To accurately calculate the triply differential cross section, including the angular behavior, it is shown that nonadiabatic wave functions for both initial and final states are required at low electron energies." @default.
- W2040806685 created "2016-06-24" @default.
- W2040806685 creator A5011650882 @default.
- W2040806685 date "2013-07-22" @default.
- W2040806685 modified "2023-10-16" @default.
- W2040806685 title "Breakup of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msup><mml:mrow><mml:msub><mml:mi mathvariant=bold>H</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:mrow><mml:mo>+</mml:mo></mml:msup></mml:math>by photon impact" @default.
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- W2040806685 doi "https://doi.org/10.1103/physreva.88.013415" @default.
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