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- W2040807681 abstract "The modification of the interface in immiscible polymer blends is critical in order to optimize physical properties. Despite the great commercial importance of polymer blends, many aspects of the emulsification process remain unclear In this paper, it will be shown that an emulsification curve can be used to estimate the influence of the architecture molar mass of styrene/hydrogenated butadiene block copolymer interfacial modifiers on the emulsifion of polystyrene/ethylene-propylene rubber blends under melt processing conditions. An expression for eing the critical amount of copolymer to saturate the interface, as well as aspects concerning the localisation of the modifier in the blend system will also be addressed. La modification de l'interface dans des mélanges de polymères immiscibles est critique pour l'optimisation des propriétés physiques. Malgré l'importance commerciales des mélanges de polymères, de nombreux aspects du processus d'émulsification demeurent obscurs. Dans cet article, on montrera qu'il est possible d'utiliser une courbe d'émulsification pour estimer l'influence de l'architecture et de la masse molaire de modificateurs interfaciaux de copolymères blocs styrène/butadiène hydrogéné sur l'émulsification de mélanges de caoutchouc polystyrène/éthylène-propylène dans des conditions de mise en forme à l'état fondu. On étudiera également une expression pour l'estimation de la quantité critique de copolymères pour saturer l'interface, ainsi que les aspects concernant la localisation du modificateur dans le système de mélange." @default.
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- W2040807681 date "1997-04-01" @default.
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- W2040807681 title "Factors influencing the efficacy of an interfacial modifier for the interface in an immiscible polymer blend" @default.
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- W2040807681 doi "https://doi.org/10.1002/cjce.5450750201" @default.
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