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- W2040807799 abstract "New highly fluorinated aromatic polyimides based on hexafluoro-2,4-toluenediamine and commercially available dianhydrides (6FDA and ODPA) were synthesized by one-pot high temperature polycondensation in benzoic acid melt. Owing to the CF3 group and fluorine atoms in the meta-linked phenylenediamine fragment, these polyimides combine good solubility in organic solvents including such a low boiling point solvent as chloroform with high glass transition temperatures (330–345 °C), thermal and thermooxidative stability (T5 is >500 °C). The highly fluorinated polyimide films (hydrogen content is ≤1%) exhibit good dielectric properties and low water absorption as well as excellent optical transparency in the UV–vis region (cut-off wavelength is 311 nm for 6FDA-based and 357 nm for ODPA-based polyimides), which is very important for optoelectronic materials." @default.
- W2040807799 created "2016-06-24" @default.
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- W2040807799 date "2011-03-01" @default.
- W2040807799 modified "2023-10-07" @default.
- W2040807799 title "Synthesis and properties of organosoluble polyimides based on novel perfluorinated monomer hexafluoro-2,4-toluenediamine" @default.
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- W2040807799 doi "https://doi.org/10.1016/j.jfluchem.2011.01.008" @default.
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