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• W2040821706 abstract "The asymmetric addition of cyclic β-keto esters to activated olefins and N-Boc imines was realized by using chiral cationic C2-symmetric N-heterocyclic carbene (NHC) Pd2+ diaqua complexes 1a,b as the catalysts, producing the corresponding adducts in moderate to high yields (up to 95%) and with good to high enantioselectivities (up to 96% ee). Nevertheless, the most significant observation is that when the (R)-NHC Pd2+ diaqua complex was used in these reactions, different absolute configurations were observed in comparison to those obtained with catalysts obtained from (R)-phosphane ligands." @default.
• W2040821706 created "2016-06-24" @default.
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• W2040821706 date "2010-06-01" @default.
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• W2040821706 title "Catalytic Enantioselective Addition of Cyclic β-Keto Esters with Activated Olefins and N-Boc Imines Using Chiral <i>C</i>₂-Symmetric Cationic Pd²⁺ N-Heterocyclic Carbene (NHC) Diaqua Complexes" @default.
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• W2040821706 doi "https://doi.org/10.1021/om100331z" @default.
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