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- W2040822056 abstract "Abstract We have synthesized and characterized poly(siloxane-g-ethylene oxide) containing Li, Na and K 2,6-di-t-butyl phenolates, and studied the effect of steric hindrance on the ionic conductivities. These polymers have a flexible siloxane main chain and the anion source bonded on it, such that only the cation can migrate. The ionic conductivity of lithium, sodium and potassium phenolate was found to be 10−7 − 10−5 s/cm at 30°C. The conductivity of Na and K salts was approximately 102 greater than that of the Li salts. This was accounted for by the improved ion pair separation in the Na and K phenolates due to the steric hindrance of the t-butyl groups. The temperature dependence of ionic conductivity suggests that the migration of ions is controlled by segmental motion of the polymer, since linear curves were obtained in VTF plots." @default.
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- W2040822056 date "1990-10-01" @default.
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- W2040822056 title "Single Ionic Conduction Based on Poly(Siloxane-g-Ethylene Oxide) Effect of Sterically Hindered Groups on Ion Dissociation" @default.
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- W2040822056 doi "https://doi.org/10.1080/00268949008047845" @default.
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