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- W2040822521 abstract "Mixtures consisting of zirconocene difluorides Cp′2ZrF2 (Cp′ = substituted or nonsubstituted η5-cyclopentadienyl) as pre-catalysts and diisobutylaluminumhydride i-Bu2AlH as activator were found to be active catalysts in the room-temperature hydrodefluorination (HDF) of fluorinated pyridines. Evaluation of these systems established rac-(ebthi)ZrF2 (1) and Cp2ZrF2 (3) together with i-Bu2AlH as active catalysts in the room-temperature hydrodefluorination (HDF) of pentafluoro-pyridine. The active species for the conversion were the actually formed hydrides [rac-(ebthi)ZrH(μ-H)]2 (2) and [Cp2ZrH(μ-H)]2 (4). The results we obtained (rt, 24 h, turn over number 67) showed a significantly better performance compared to other investigations published before for this HDF reaction." @default.
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- W2040822521 date "2007-01-01" @default.
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- W2040822521 title "Room-temperature catalytic hydrodefluorination of pentafluoro-pyridine by zirconocene fluoro complexes and diisobutylaluminumhydride" @default.
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- W2040822521 doi "https://doi.org/10.1016/j.molcata.2006.06.027" @default.
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