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- W2040856544 abstract "A series of highly active, selective, and stable silver-exchanged phosphotungstic acid (AgPW) catalysts were prepared, characterized, and evaluated for bio-derived glycerol esterification with acetic acid to produce valuable biofuel additives. The structures, morphologies, acidities, and water tolerance of these samples were determined by FTIR, Raman, XRD, SEM-EDX, FT-IR of pyridine adsorption, and H2O-TPD. Several typical acidic catalysts were also performed for comparison. Among them, partially silver-exchanged phosphotungstic acid (Ag1PW) presented exceptionally high activity, with 96.8% conversion within just 15 min of reaction time and remarkable stability, due to the unique Keggin structure, high acidity as well as outstanding water-tolerance property. A plausible reaction mechanism was also proposed. In addition, this Ag1PW catalyst exhibited universal significance for esterification, holding great potential for a wide range of other acid-catalyzed reactions." @default.
- W2040856544 created "2016-06-24" @default.
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- W2040856544 date "2013-10-01" @default.
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- W2040856544 title "Design of a highly active silver-exchanged phosphotungstic acid catalyst for glycerol esterification with acetic acid" @default.
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- W2040856544 doi "https://doi.org/10.1016/j.jcat.2013.06.026" @default.
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