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- W2040871970 abstract "Abstract The i.r. spectra are reported of argon matrix isolated complexes formed between trifluoroacetic acid and hydrogen chloride and between their deuterated analogues. The pattern of bands characteristic for 1:1 complex indicates that a cyclic complex is formed in which each component acts both as a proton donor and as a proton acceptor. The bands due to 1:2 complexes are also identified in the spectra of matrices containing an excess of HCl. The results of CNDO/2 calculations with molecular geometry optimalization for CF 3 COOHHF model system in different geometric arrangements are presented. In agreement with presented experimental data the cyclic heterodimer with the interaction energy equal to 103.90 kJ mol −1 is of the most stable structure." @default.
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- W2040871970 date "1982-01-01" @default.
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- W2040871970 title "at]Infrared matrix isolation and CNDO/2 studies of complexes between trifluoroacetic acid and hydrogen halides" @default.
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- W2040871970 doi "https://doi.org/10.1016/0584-8539(82)80123-2" @default.
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