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• W2040873105 abstract "The synthesis and chemical behavior of the intra- and intermolecular donor-stabilized silanediyl complexes (C6H4CH2NMe2-2)(Cl)SiMLn (4, MLn = Cr(CO)5 5, MLn = Fe(CO)4), (C6H5HCCH)(Cl)Si=MLn·OP(NMe2)3 (21, MLn = Cr(CO)5; 22, MLn = Fe(CO)4), and (C6H5HCCH)(C6H5)SiFe(CO)4·OP(NMe2)3 (23) is discussed. Nucleophilic substitution of the chloro atom in compounds 4 and 5 by different nucleophiles leads to a great variety of further functionalized silanediyl complexes of the type (C6H4CH2NMe2-2)(R)SiMLn (MLn = Cr(CO)5: 7, R = CH3; 9, R = C6H5; 11, R = P(C6H5)2; 13, R = CHCH2. MLn = Fe(CO)4: 14, R = CHCH2; 15, R = CH3). Moreover, the 1-metalla-2-sila-1,3-dienes (C6H4CH2NMe2-2)(H2CCH)Si=MLn (13, MLn = Cr(CO)5; 14, MLn = Fe(CO)4) can be prepared by treatment of the hypervalent dichlorosilane (C6H4CH2NMe2-2)(H2CCH)SiCl2 (19) with the carbonylate dianions MLn2- (2, MLn = Cr(CO)5; 3, MLn = Fe(CO)4). Additionally, compounds of the latter type are accessible by photochemical coupling reactions of the pentavalent silane (C6H4CH2NMe2-2)(CH3)SiH2 (16) with the transition-metal carbonyls Cr(CO)6 (17a), Fe(CO)5 (17b), and (η5-C5H5)Mn(CO)3 (17c), respectively. The intermolecular donor-stabilized 1-metalla-2-sila-1,3-dienes 21−23 can be prepared by the reaction of tetravalent dichlorosilanes [(R)(H)CCH](R‘)SiCl2 (20a, R = H, R‘ = Cl; 20b, R = R‘ = C6H5) with the carbonylmetalates 2 and 3 and in the presence of OP(NMe2)3." @default.
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• W2040873105 date "1998-06-26" @default.
• W2040873105 modified "2023-10-08" @default.
• W2040873105 title "New Investigations in Silanediyl Complex Chemistry: Synthesis, Structure, and Bonding of 1-Metalla-2-sila-1,3-dienes" @default.
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• W2040873105 doi "https://doi.org/10.1021/om980032j" @default.
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