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• W2040876167 abstract "Abstract The emission of protons from the polycrystalline CeO x surface was investigated during noble-gas ion bombardment ( E 0 E 0 =100 eV). At the reduced CeO x surface, the proton survives neutralization with a higher probability when scattered from oxygen than from cerium. The surface hydrogens are sputtered as protons by ion irradiation via the non-collisional electronic transition. The probability for H + desorption decreases in order of He + , Ne + and Ar + . This is because hydrogen desorbs from the antibonding OH group with an O 2s core hole which is created via the quasi-resonant charge exchange with the primary ions. The ionization of hydrogen occurs during the O–H bond breakage via the interatomic Auger decay of the O 2s hole. The resulting H + ion survives neutralization preferentially from O of CeO 2 as confirmed from the H + scattering experiment. On the basis of these findings, we propose resonant ion stimulated desorption (RISD) as a tool for quite sensitive detection of surface hydroxyl group and apply it to in situ observations of hydrogen segregation to the surface." @default.
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• W2040876167 date "2000-02-01" @default.
• W2040876167 modified "2023-10-01" @default.
• W2040876167 title "Resonant ion stimulated desorption of protons from cerium oxide" @default.
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• W2040876167 doi "https://doi.org/10.1016/s0168-583x(99)00590-x" @default.
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