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• W2040886893 abstract "27Al and 29Si NMR spectra and spin–lattice relaxation in heavily sodium-doped sodalite Na8(AlSiO4)6 are presented. The magnetic hyperfine shifts of 27Al and 29Si have Curie–Weiss-type temperature dependences with the same Weiss parameter Θ=−168±5 K. From an abrupt broadening of the resonance lines the transition temperature to the antiferromagnetic phase TN=54±2 K is determined. Above 200 K thermally activated ionic motion (activation energy, EA/kB=2000 K) is found in sodalite cages containing Na43+ ions which is much slower than the motion (EA/kB=750 K) in the cages containing Na33+ ions." @default.
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• W2040886893 date "2000-09-01" @default.
• W2040886893 modified "2023-10-18" @default.
• W2040886893 title "NMR study of antiferromagnetic black sodalite Na8(AlSiO4)6" @default.
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• W2040886893 doi "https://doi.org/10.1016/s0009-2614(00)00859-9" @default.
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