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- W2040886937 abstract "Abstract In order to get materials with enhanced adsorption and photocatalytic performance, nanosized silver particles loaded TiO 2 was prepared by a facile photodeposition. This catalyst was characterized by X-ray diffraction (XRD), high resolution transmission electron microscopy (HR-TEM), X-ray photoelectron spectroscopy (XPS), Brunauer–Emmett–Teller surface area (BET) and diffuse reflectance spectroscopy (DRS). XRD patterns revealed that the crystal structure of Ag–TiO 2 resembled anatase phase of TiO 2 . Visible light absorption increases with the increase in Ag loading. Photoluminescence spectra indicate the suppression of recombination of the photogenerated electron-hole pairs by the loaded silver on TiO 2 . XPS measurements reveal the presence of silver particles mainly in metallic form. 1.5% Ag loaded TiO 2 is found to be most efficient for selective one-pot synthesis of quinaldines from nitroarenes in ethanol using UV light. Ag–TiO 2 on irradiation induces a combined redox reaction with nitroarene and alcohol and this is followed by condensation-cyclization of aniline and oxidation products to give quinaldines." @default.
- W2040886937 created "2016-06-24" @default.
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- W2040886937 date "2011-12-01" @default.
- W2040886937 modified "2023-09-25" @default.
- W2040886937 title "Cost effective one-pot photocatalytic synthesis of quinaldines from nitroarenes by silver loaded TiO2" @default.
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- W2040886937 doi "https://doi.org/10.1016/j.molcata.2011.09.014" @default.
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