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• W2040890141 abstract "We studied the physical properties of Sr2VO4 with a K2NiF4 structure in polycrystalline forms synthesized under various different conditions. We found that stoichiometric samples or those with nominal hole doping into the d1 state of the V ion exhibit insulating behavior with an antiferromagnetic interaction between V moments, whereas those with nominal electron doping exhibit metallic conduction and ferromagnetic interaction. A structural phase transition at Tc ∼ 100 K, which is likely to be associated with the orbital ordering of the V4+ ion, is observed only in the former sample exhibiting a sharp drop in the magnetic susceptibility at the same temperature, whereas no structural anomaly was observed for the sample exhibiting a cusp in the magnetic susceptibility at ∼50 K." @default.
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• W2040890141 date "2014-03-15" @default.
• W2040890141 modified "2023-09-25" @default.
• W2040890141 title "Effect of Offstoichiometry on the Physical Properties of Sr2VO4" @default.
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• W2040890141 doi "https://doi.org/10.7566/jpsj.83.034708" @default.
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