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• W2040915519 startingPage "1138" @default.
• W2040915519 abstract "We report a metallic state in a nanostructured porous crystal 12CaO·7Al2O3 by incorporating electrons in the inherent subnanometer-sized cages, in which a three-dimensionally closely packed cage structure acts as an electronic conduction path. High-density electron doping (∼2 × 1021 cm-3), which was achieved by a thermal treatment in Ti metal vapor at ∼1100 °C, induces homogenization of the cage geometry to a symmetric state, resulting in an insulator−metal transition with a sharp enhancement of the electron drift mobility from ∼0.1 to 4 cm2 V-1 s-1. The results provide an approach for the realization of electroactive functions in materials composed only of environmentally benign elements by utilizing the appropriate nanostructures." @default.
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• W2040915519 date "2007-03-22" @default.
• W2040915519 modified "2023-10-05" @default.
• W2040915519 title "Metallic State in a Lime−Alumina Compound with Nanoporous Structure" @default.
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• W2040915519 doi "https://doi.org/10.1021/nl062717b" @default.
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• W2040915519 hasPublicationYear "2007" @default.
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