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• W2040942875 abstract "Photofragment yield spectra of jet-cooled CH3ONO are measured over the first few resonances of the S1 ← S0 absorption by monitoring the NO fragments via selected rotational levels in each of the four sublevels F1 (A′, A″) and F2 (A′, A″) of the vibrational states v″ = 0, 1 and 2. Based on spectral features, the 000 transitions of the anti-and syn-isomers were assigned to the bands at 25600 ± 30 and 26160 ± 30−1, respectively, supporting, in combination with vibrational state distributions, the dominance of a vibrationally non-adiabatic over an adiabatic dissociation process. The observed linewidth of the vibronic absorption bands of ≈ 500 cm−1, which is essentially unchanged from that at room temperature, remains unexplained." @default.
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• W2040942875 date "1993-07-01" @default.
• W2040942875 modified "2023-09-23" @default.
• W2040942875 title "Photofragment yield spectra of methyl nitrite in a supersonic jet" @default.
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• W2040942875 doi "https://doi.org/10.1016/0009-2614(93)80107-z" @default.
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