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- W2040955377 abstract "In this paper, the kinetic relationships with regard to the informations of 2212 and 2223 superconducting phases have been studied for a Bi-based superconductor with 2223 nominal composition. The formation of the Pb-doped 2223 phase and the 2212 phase with or without Pb obey the nucleation and crystal growing model, whose kinetic equations are Qi=1−exp (−Kitn), whereas the formation of 2223 phase in the Pb-free system belongs to the nucleus boundary shrinking model, and the equation is 1−(1−Q2223)13=K2223t. It is proved that the factor controlling phase formation is the activation energy of the overall reaction. The optimum sintering temperature range for the formation and the transformation relationships between the high-temperature phase and low-temperature phase are discussed." @default.
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- W2040955377 date "1994-08-01" @default.
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- W2040955377 title "The kinetic relationships and activation energy of Bi-based superconducting phase formation" @default.
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- W2040955377 doi "https://doi.org/10.1016/0921-4534(94)90820-6" @default.
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