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- W2040957377 abstract "In <sup>1</sup>H NMR spectra of four nucleosides of uracil and thymine - U, dU, T and rT - in anhydrous DMSO in the presence of carboxylate-ion there was observed disappearance of signals of the N3H aglycon protons and all the hydroxyl protons of glycosylic fragments. This changes were interpreted as a result of the N3H - 02H proton transfer in the base residues under the complex formation between nucleosides and ligand molecules: one carboxylate-ion forms two H-bonds with groups 02H and 05'H, another - two H-bonds with hydroxyl groups 02'H and 03'H in the case of a riboside or one Hbond with group 03'H of a deoxyriboside. Orders ofthe complexes' stability were established, which from, particularly, the conclusion was drawn that the canonical nucleosides U and T form more stable complexes with carboxylate-ion, than metabolites dU and rT. Biological significance ofthe results obtained is pointed out." @default.
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- W2040957377 date "2004-07-20" @default.
- W2040957377 modified "2023-10-14" @default.
- W2040957377 title "<title>Tautomeric transition in uracil and thymine nucleosides induced by deprotonated carboxylic group: <formula><sup><roman>1</roman></sup></formula>H NMR data</title>" @default.
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- W2040957377 doi "https://doi.org/10.1117/12.570015" @default.
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