Matches in SemOpenAlex for { <https://semopenalex.org/work/W2040978089> ?p ?o ?g. }
Showing items 1 to 90 of
90
with 100 items per page.
- W2040978089 endingPage "206" @default.
- W2040978089 startingPage "201" @default.
- W2040978089 abstract "The equilibrium constant (K) of photochemical inversion between Δ- and Λ-[Ru(S-am)(bpy)2]+ (bpy=2, 2′- bipyridine (bpy); S-am=(S)-alaninato (S-Ala), (S)-phenylglycinato (S-Phg), (S)-leucinato (S-Leu), (S)-phenylalaninato (S-Phe) or (S)-tyrosinato (S-Tyr) ligand) was obtained in H2O, D2O, CH3OH and CH3CNH2O (1:1 in molar ratio) solutions at temperatures of 0 to 100 °C, and ΔH° and ΔS° were estimated. The hydrophilic solvation favored the Δ isomer in water, appearing on the enthalpy difference, and the hydrophobic solvation preferred the Λ isomer, controlling the entropy difference. These opposite effects dominated the stability of the two isomers of the complex containing the S-Leu, S-Phe or S-Tyr ligand in water. The results suggested the importance of intramolecular hydrophobic bonding. The photochemical inversion hardly occurred in pure acetonitrile." @default.
- W2040978089 created "2016-06-24" @default.
- W2040978089 creator A5083117280 @default.
- W2040978089 date "1993-06-01" @default.
- W2040978089 modified "2023-10-18" @default.
- W2040978089 title "Effect of hydrophobic and hydrophilic interactions on the stability of diastereoisomers of Δ- and Λ-[Ru(S-am)(bpy)2]+ complexes (am=Ala, Phg, Leu, Phe or Tyr ligand) in aqueous solutions" @default.
- W2040978089 cites W1970393749 @default.
- W2040978089 cites W1975973409 @default.
- W2040978089 cites W2004268218 @default.
- W2040978089 cites W2004387962 @default.
- W2040978089 cites W2025228532 @default.
- W2040978089 cites W2026762739 @default.
- W2040978089 cites W2030553677 @default.
- W2040978089 cites W2054250807 @default.
- W2040978089 cites W2055929214 @default.
- W2040978089 cites W2059933216 @default.
- W2040978089 cites W2060658562 @default.
- W2040978089 cites W2062416956 @default.
- W2040978089 cites W2065675637 @default.
- W2040978089 cites W2072516875 @default.
- W2040978089 cites W2331129251 @default.
- W2040978089 cites W2951643268 @default.
- W2040978089 cites W3137933544 @default.
- W2040978089 cites W1970590925 @default.
- W2040978089 doi "https://doi.org/10.1016/s0020-1693(00)85122-1" @default.
- W2040978089 hasPublicationYear "1993" @default.
- W2040978089 type Work @default.
- W2040978089 sameAs 2040978089 @default.
- W2040978089 citedByCount "2" @default.
- W2040978089 crossrefType "journal-article" @default.
- W2040978089 hasAuthorship W2040978089A5083117280 @default.
- W2040978089 hasConcept C116569031 @default.
- W2040978089 hasConcept C121332964 @default.
- W2040978089 hasConcept C138716334 @default.
- W2040978089 hasConcept C147789679 @default.
- W2040978089 hasConcept C148093993 @default.
- W2040978089 hasConcept C155647269 @default.
- W2040978089 hasConcept C170493617 @default.
- W2040978089 hasConcept C178790620 @default.
- W2040978089 hasConcept C184651966 @default.
- W2040978089 hasConcept C185592680 @default.
- W2040978089 hasConcept C2777463227 @default.
- W2040978089 hasConcept C3288061 @default.
- W2040978089 hasConcept C32909587 @default.
- W2040978089 hasConcept C55493867 @default.
- W2040978089 hasConcept C71240020 @default.
- W2040978089 hasConcept C75079739 @default.
- W2040978089 hasConcept C8010536 @default.
- W2040978089 hasConcept C90260826 @default.
- W2040978089 hasConcept C97355855 @default.
- W2040978089 hasConceptScore W2040978089C116569031 @default.
- W2040978089 hasConceptScore W2040978089C121332964 @default.
- W2040978089 hasConceptScore W2040978089C138716334 @default.
- W2040978089 hasConceptScore W2040978089C147789679 @default.
- W2040978089 hasConceptScore W2040978089C148093993 @default.
- W2040978089 hasConceptScore W2040978089C155647269 @default.
- W2040978089 hasConceptScore W2040978089C170493617 @default.
- W2040978089 hasConceptScore W2040978089C178790620 @default.
- W2040978089 hasConceptScore W2040978089C184651966 @default.
- W2040978089 hasConceptScore W2040978089C185592680 @default.
- W2040978089 hasConceptScore W2040978089C2777463227 @default.
- W2040978089 hasConceptScore W2040978089C3288061 @default.
- W2040978089 hasConceptScore W2040978089C32909587 @default.
- W2040978089 hasConceptScore W2040978089C55493867 @default.
- W2040978089 hasConceptScore W2040978089C71240020 @default.
- W2040978089 hasConceptScore W2040978089C75079739 @default.
- W2040978089 hasConceptScore W2040978089C8010536 @default.
- W2040978089 hasConceptScore W2040978089C90260826 @default.
- W2040978089 hasConceptScore W2040978089C97355855 @default.
- W2040978089 hasIssue "2" @default.
- W2040978089 hasLocation W20409780891 @default.
- W2040978089 hasOpenAccess W2040978089 @default.
- W2040978089 hasPrimaryLocation W20409780891 @default.
- W2040978089 hasRelatedWork W2019571757 @default.
- W2040978089 hasRelatedWork W2037091577 @default.
- W2040978089 hasRelatedWork W2060083339 @default.
- W2040978089 hasRelatedWork W2061861540 @default.
- W2040978089 hasRelatedWork W2085216439 @default.
- W2040978089 hasRelatedWork W2110386563 @default.
- W2040978089 hasRelatedWork W2114852715 @default.
- W2040978089 hasRelatedWork W238896092 @default.
- W2040978089 hasRelatedWork W2784241993 @default.
- W2040978089 hasRelatedWork W2951314393 @default.
- W2040978089 hasVolume "208" @default.
- W2040978089 isParatext "false" @default.
- W2040978089 isRetracted "false" @default.
- W2040978089 magId "2040978089" @default.
- W2040978089 workType "article" @default.