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• W2040983805 abstract "Abstract We present our Raman scattering investigation on a new phase of the organic crystal (BEDT-TTF)2I3, which was first synthesized by Zhu et al. using a diffusion method. The Raman spectra are taken with excitation wavelengths of 4579 A and 5145 A, and at several temperatures above and below ∼140 K, the metal-semiconductor phase transition temperature observed by measurements of transport properties. The results show that the I3 chains in the crystal may undergo an order-disorder structural transition at this temperature. A picture is proposed in which the structural transition of I3 chains from a somewhat randomly arranged high-temperature state to the ordered low-temperature state may result in the decreased overlap of two electron energy bands, and hence cause the 140 K metal-semiconductor phase transition." @default.
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• W2040983805 date "1989-07-01" @default.
• W2040983805 modified "2023-09-26" @default.
• W2040983805 title "Raman scattering investigations of the organic crystal βd′ -(BEDT-TTF)2I3" @default.
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• W2040983805 doi "https://doi.org/10.1016/0379-6779(89)90625-5" @default.
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