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• W2040986040 abstract "The room temperature reaction of NiBr2(NCCH3)x with the pincer-type ligand POCHOPPh gave the new pincer complex (POCOPPh)NiBr (1, POCOPPh = κP, κC, κP-2,6-{Ph2PO}2C6H3). Complex 1 reacts with AgX to give the analogous Ni–X derivatives (X = CN, 2; OSO2CF3, 3; OC(O)CH3, 4; ONO2, 5), whereas complex 3 reacts with phenylacetylene and NEt3 to give the Ni–CCPh derivative 6. On the other hand, reaction of 1 or 3 with RLi or RMgI did not afford the desired Ni–R derivatives, giving instead the corresponding iodo and hydroxo derivatives. Complexes 1–6 have been characterized by NMR, IR, and UV-Vis spectroscopy and X-ray crystallography. The solid state structural and IR data indicate that Ni–Csp interaction is dominated by ligand-to-metal σ-donation in 2 and 6. Cyclic voltammetry measurements indicate that complexes 3 and 4 display reversible redox behaviour (NiII/NiIII); comparison of the E01/2 values for these complexes and their POCOPi-Pr analogues shows that both the X ligands and the P-substituent have a considerable impact on the ease of oxidation in this family of complexes." @default.
• W2040986040 created "2016-06-24" @default.
• W2040986040 creator A5023746597 @default.
• W2040986040 creator A5041877922 @default.
• W2040986040 date "2011-01-01" @default.
• W2040986040 modified "2023-10-18" @default.
• W2040986040 title "The impact of P-substituents on the structures, spectroscopic properties, and reactivities of POCOP-type pincer complexes of nickel(ii)" @default.
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• W2040986040 doi "https://doi.org/10.1039/c1dt10381d" @default.
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