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- W2040989700 abstract "The influence of molybdate anions on the pitting corrosion resistance of Fe in neutral Cl−-containing borate buffer (pH 8.4) solutions were investigated. The presence of molybdate in the solution was found to inhibit pitting corrosion of Fe. However, a complete protection in potentiodynamic experiments can only be achieved with NaCl concentration of 0.01 M; in solutions containing 0.1 M NaCl, pitting corrosion occurs even with high concentration of molybdate (1 M). Potentiostatic experiments at potentials below the pitting potential were carried out to study metastable pitting events observed as current transients. In solutions containing molybdate, a significantly smaller number of large current transients are observed than in the absence of molybdate. The largest current transients, detected in the potential region slightly negative to the pitting potentials, have shorter lifetimes in the presence of molybdate in the solution. Hence, molybdate enhances repassivation. Analysis of the corrosion products in stable pits clearly indicate that Cl− is replaced by molybdate. Therefore, the facilitated repassivation can be due to precipitation of sparingly soluble Fe-molybdates in the pit, which act as a pre-cursor film for passivation." @default.
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- W2040989700 date "2001-06-01" @default.
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- W2040989700 title "Influence of MoO42− anion in the electrolyte on passivity breakdown of iron" @default.
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- W2040989700 doi "https://doi.org/10.1016/s0010-938x(00)00121-9" @default.
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