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- W2040992080 endingPage "146" @default.
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- W2040992080 abstract "The new metal complexes {[(R)-(S)-Pigiphos]Rh(CH3CN)3}Y3 (Y=PF6, (3a); OTf, (3b)) and {[(R)-(S)-Pigiphos]Ni(CH3CN)}(BF4)2 (4) containing the chiral bis-ferrocenyl triphosphine ligand (R)-(S)-Pigiphos have been synthesized and used as catalyst precursors for the acetalization of aldehydes and ketones with glycols. The reactions occur in mild conditions and require the presence of molecular sieves as drying agent. The yields are generally excellent, but no significant diastereo- or enantioselectivity is observed." @default.
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- W2040992080 date "1999-09-01" @default.
- W2040992080 modified "2023-10-11" @default.
- W2040992080 title "Synthesis and characterization of chiral bis-ferrocenyl triphosphine Ni(II) and Rh(III) complexes and their use as catalyst precursors for acetalization reactions" @default.
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- W2040992080 doi "https://doi.org/10.1016/s1381-1169(99)00016-3" @default.
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