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- W2041011607 abstract "3,8-Diformyldeuteroporphyrin dimethyl ester (1a) was obtained by ozonization of the diprotonated dication of protoporphyrin dimethyl ester 1b. Several derivatives have been prepared, which are either hydrophobic, or bear hydrophilic substituents in the „northern hemisphere” of the porphyrin ligand or on both sides. The porphyrins have then been dissolved in aqueous media containing vesicles with electroneutral, -negative, or -positive surface charges. The localization of the dissolved porphyrin chromophore was determined spectroscopically following reactions of the central porphyrin nitrogen atoms or of peripheral substituents with water-soluble acids or metal ions.Metalloporphyrine in polymeren Matrizen. Mizellen und Vesikeln, VI. - Hydrophobe und hydrophile Derivate des 3,8-Diformyldeuteroporphyrin-dimethylesters und ihre Wechselwirkung mit Vesikeln3,8-Diformyldeuteroporphyrin-dimethylester (1a) wurde durch Ozonisierung des diprotonierten Dikations von Protoporphyrin-dimethylester 1b erhalten. Mehrere Derivate wurden dargestellt, die entweder hydrophobe Eigenschaften aufweisen oder hydrophile Substituenten in der “nordlichen Hemisphare” des Porphyrinliganden oder an beiden Seiten tragen. Die Porphyrine wurden in wasrigen Medien gelost, die Vesikel mit elektroneutralen, -negativen oder -positiven Oberflachenladungen enthielten. Der Aufenthaltsort der gelosten Porphyrine wurde durch den spektroskopischen Nachweis von Reaktionen der zentralen Porphyrin-Stickstoffatome oder von peripheren Substituenten mit wasserloslichen Sauren oder Metall-Ionen bestimmt." @default.
- W2041011607 created "2016-06-24" @default.
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- W2041011607 date "1984-06-12" @default.
- W2041011607 modified "2023-09-27" @default.
- W2041011607 title "Metalloporphyrins in Polymeric Matrices, Micelles, and Vesicles, VI. Hydrophobic and Hydrophilic Derivatives of 3,8-Diformyl-deuteroporphyrin Dimethyl Ester and their Interaction with Vesicles" @default.
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- W2041011607 doi "https://doi.org/10.1002/jlac.198419840602" @default.
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