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- W2041012352 abstract "The replacement of xenon(+) by iodine in reactions of alkenylxenonium(II) salts [RCF=CFXe]Y (R = cis-C2F5, trans-H) and alkynylxenonium(II) salt [C3F7C≡CXe][BF4] with NaI in anhydrous HF (aHF) occurred regiospecifically. At −60 °C the substitution of xenon(+) by bromine in the perfluorinated salts [cis-CF3CF=CFXe]Y and [trans-C4F9CF=CFXe]Y proceeded regio- and stereospecifically with NaBr in aHF, but at a higher temperature and after a longer time the treatment of [cis-C2F5CF=CFXe]Y with NaBr, KBr, or [NBu4]Br in aHF gave mixtures of cisand trans-perfluorobut-1-enyl bromides. The reaction of [C3F7C≡CXe][BF4] with NaBr in aHF at −65 °C gave only 48 %, of C3F7C≡CBr and was accompanied by a mixture of bromine-containing related olefins. Reaction pathways to the main product are discussed." @default.
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- W2041012352 date "2007-08-01" @default.
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- W2041012352 title "Reactions of Alk-1-enylxenonium(II) and Alk-1-ynylxenonium(II) Salts [RXe]Y with Bromides and Iodides in Anhydrous HF" @default.
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- W2041012352 doi "https://doi.org/10.1002/zaac.200700075" @default.
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