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• W2041031886 abstract "The solvation parameter model is used to construct models for the estimation of the soil-water and soil-air distribution constants and to characterize the contribution of fundamental intermolecular interactions to the underlying sorption processes. Wet soil is shown to be quite cohesive and polar but relatively non-selective for dipole-type, lone-pair electron and hydrogen-bond interactions. Using a comparison of system constant ratios chromatographic systems employing reversed-phase liquid chromatography on polar bonded phases are shown to provide suitable models for estimating soil-water distribution constants. No suitable gas chromatographic models were found for the soil-air distribution constant but the requirements for such a system are indicated. Models are also provided for adsorption at the air-water interface. Estimation methods based on either the solvation parameter model or chromatographic model reproduce experimental distribution constants for a wide variety of compounds with a similar error (0.2-0.3 log units) to that expected in the experimental data." @default.
• W2041031886 created "2016-06-24" @default.
• W2041031886 creator A5042984744 @default.
• W2041031886 creator A5057641128 @default.
• W2041031886 date "1999-06-01" @default.
• W2041031886 modified "2023-10-17" @default.
• W2041031886 title "Chromatographic models for the sorption of neutral organic compounds by soil from water and air" @default.
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• W2041031886 doi "https://doi.org/10.1016/s0021-9673(98)01085-1" @default.
• W2041031886 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/10399340" @default.
• W2041031886 hasPublicationYear "1999" @default.
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