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- W2041058811 abstract "On the basis of the flow study presented in Part I the desorption behaviour of the isobaric laboratory adsorber is investigated. The investigation is suitable to identify the micropore diffusion mechanism of NH3 molecules in A-type zeolite crystals. The sorption system is characterized by the fact that the diameter of diffusing molecules is of the same magnitude as the micropore diameter. For such systems, Gutsche et al. predicted the concentration dependence of Fickian diffusivity to obey the relation DzDz0 da/dq. This relation is a special form of a more general equation derivable from transition state theory. In the present work, the concentration dependence of NH3 diffusivities is found to satisfy the above relation. With this result, an experimental support for the prediction of Gutsche is provided." @default.
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- W2041058811 date "1993-11-01" @default.
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- W2041058811 title "Concentration-dependent micropore diffusion analysed by measuring laboratory adsorber dynamics—II. Study of the micropore diffusion mechanism" @default.
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- W2041058811 doi "https://doi.org/10.1016/0009-2509(93)81030-y" @default.
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