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- W2041058819 abstract "Abstract The electron-vibrational (vibronic) bands of light absorption by mixed valence molecular crystals containing clusters of transition metal ions in different states of oxidation as the structural units of lattice are considered. The absorption band shape calculation in different phase states is performed in the semiclassical limit for crystals consisting of trielectronic clusters of transition metals of the type of d1-d2. The band shape differs from the Gaussian and closely depends on the double-exchange and Heisenberg-type exchange parameters and on the temperature dependence of the average dipole moment playing the role of the order parameter." @default.
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- W2041058819 date "1990-06-01" @default.
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- W2041058819 title "Charge Transfer Bands of Mixed Valence Molecular Crystals" @default.
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- W2041058819 doi "https://doi.org/10.1080/00387019008054445" @default.
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