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- W2041060768 abstract "We have observed for the first time a small, linear Zeeman effect of low-lying crystal field excitations in insulating PrF3 by means of Raman spectroscopy. As the crystal field of low symmetry in PrF3 completely quenches the magnetic moments of the single Pr3+-ions, this observation strongly supports the previously given interpretation of the Raman and farinfrared spectra of PrF3 using the Frenkel-exciton model for the 4f-excitations of the lowest multiplet component interacting with the system of optical phonons. By a simple technique, which uses the orthogonal polarization of the light scattered by two Zeeman-components and a computerized spectrometer, we were able to resolve Zeeman splittings smaller than 0.1 cm-1. The results are in agreement with theoretical predictions based on a purely phonon-mediated Pr-Pr interaction." @default.
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- W2041060768 date "1987-10-15" @default.
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- W2041060768 title "Nonlocalized Magnetic Moments in the Weak Van Vleck Paramagnet PrF <sub>3</sub>" @default.
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- W2041060768 doi "https://doi.org/10.1209/0295-5075/4/8/012" @default.
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