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• W2041074579 abstract "[reaction--see text] Enolates of a new camphor-derived lactam auxiliary are shown to monoalkylate with very high diastereoselectivity. A second alkylation occurs with reactive alkylating agents to afford quaternary centers also with high diastereoselectivity. In accord with a proposed model for diastereoselection, lithium and sodium enolates provide products with an opposite sense of asymmetric induction." @default.
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• W2041074579 date "2001-10-13" @default.
• W2041074579 modified "2023-10-11" @default.
• W2041074579 title "Toward the Development of a General Chiral Auxiliary. 9. Highly Diastereoselective Alkylations and Acylations to Form Tertiary and Quaternary Centers" @default.
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• W2041074579 doi "https://doi.org/10.1021/ol016738i" @default.
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