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- W2041105609 abstract "The free-radical-initiated copolymerization of 2,6-dichloro-styrene (2,6-DClSt), with maleimide (MI), N-methylmaleimide (NMeMI) and N-phenylmaleimide (NPhMI) was carried out in butanone or in toluene at 65°C with different monomer-to-monomer ratios in the feed. The copolymer composition was evaluated by chlorine content in polymers. The reactivity ratios determined by Kelen-Tudos method indicate the random arrangement of monomers in copolymer chains. In all studied systems, azeotropic points were observed at ratios of: 0.5 (2,6-DClSt) to 0.5 (MI) and 0.4 (2,6-DClSt) to 0.6 (NMeMI and NPhMI). Molecular weights of copolymer, which contain equimolar ratio of 2,6-DClSt-co-MI, NMeMI, and NPhMI are: Mw· 10−3 = 46.1; 90.4; 81.4. Mn 10−3 = 27.1; 46.0; 37.0. The copolymers are thermostable, film forming materials, which decompose by one-step mechanism between 400°C, and 500°C. The Tg's are linearly distributed between Tg's of homopolymers and in all cases, single well defined Tg's are obtained." @default.
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- W2041105609 title "FREE RADICAL-INITIATED COPOLYMERIZATION OF 2,6-DICHLOROSTYRENE WITH MALEIMIDE, N-METHYLMALEIMIDE, AND N-PHENYLMALEIMIDE" @default.
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- W2041105609 doi "https://doi.org/10.1081/ma-100101107" @default.
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