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- W2041128804 abstract "Abstract: This report describes the development of an efficient solid-phase synthesis protocol and adaptation of reported solution phase procedures for the synthesis of the cyclic depsihexapeptide destruxin A and related analogs. The solid-phase method described is based on standard Fmoc peptide chemistry, including a new synthetic method for the assembly of the depsi bond-containing unit. In order to select analogs of destruxin A for synthesis and evaluation of insecticidal activity, the work of Hellberg et al., describing a set of Z-descriptors for amino acid side-chains comparing their physicochemical properties, was utilized. Destruxin A and 27 different analogs with structural variations in four residues were synthesized and insecticidal activity was evaluated via injections into tobacco budworm (Heliothis virescens) larvae. Several destruxin A analogs were found to be at least as potent as the native compound." @default.
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- W2041128804 date "2001-07-01" @default.
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- W2041128804 title "Synthesis and biological evaluation of destruxin A and related analogs" @default.
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- W2041128804 doi "https://doi.org/10.1034/j.1399-3011.2001.00856.x" @default.
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