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- W2041128903 abstract "Abstract Kinetic results are reported for reactions of hexa-aquozinc(II) ion and several zinc(II) complexes with aminopoly-carboxylate ligands and some bidentate ligands. Factors which alter “normal” kinetic behavior in these systems are demonstrated and discussed: the effect of complex geometry, of proton transfer, and of six-membered ring closure. Other features of these reactions and mechanisms are also discussed. Differences in kinetic behavior observed for reaction of maleonitriledithiolate (mnt2-) with Zn(NTA)− and for similar reactions with Cu(NTA)− and Ni(NTA)− suggest differences in structure for the respective NTA complexes (NTA3-=nitrilotriacetate). Proton transfer from NTAH2- is believed to control the rates of reaction with Zn(H2O)6 2+ and Zn(dto)2 2- (dto2-=dithiooxalate). The behavior of EDTA in reaction with zinc complexes is compared with that of two analogues that form six-membered chelate rings." @default.
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- W2041128903 date "1973-02-01" @default.
- W2041128903 modified "2023-09-25" @default.
- W2041128903 title "KINETIC BEHAVIOR OF AMINOPOLYCARBOXYLATE LIGANDS IN SUBSTITUTION REACTIONS OF Zn(II) COMPLEXES" @default.
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- W2041128903 doi "https://doi.org/10.1080/00958977308072969" @default.
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