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• W2041155712 abstract "The three-dimensional hybrid compound Ni3(C4H4N2)3(V8O23) has been synthesized by mild hydrothermal methods under autogenous pressure at 170 °C. The structure of the phase is stable until 380 °C. The removal of the pyrazine molecules from the structure induces its collapse. The IR spectrum shows the vibration modes of the pyrazine molecule and those of the [VO4]3− groups. A UV–visible spectrum shows the characteristic bands of the Ni(II) d8-high-spin cation in a slightly distorted octahedral coordination. Magnetic measurements indicate the existence of antiferromagnetic interactions that can be fitted with a chain model to give g = 2.31, J/k = −5.3, and zJ′/k = −5.5." @default.
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• W2041155712 date "2011-06-01" @default.
• W2041155712 modified "2023-10-14" @default.
• W2041155712 title "Hydrothermal synthesis and study of an inorganic–organic hybrid vanadate of a nickel(II) coordination complex with pyrazine, Ni3(C4H4N2)3(V8O23)" @default.
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• W2041155712 doi "https://doi.org/10.1016/j.materresbull.2011.02.033" @default.
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