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- W2041177124 abstract "A [2]catenane, composed of a π-electron-rich bis-1,5-dioxynaphthalene[38]crown10 (BDNP38C10) ring, mechanically interlocked with a large macrocycle containing two disubstituted tetraarylmethane “speed bumps” and two different π-electron-deficient units—namely, naphthalene dimide (NpI) and bipyridinium (BIPY2+) units—has been synthesized from a [2]rotaxane, containing the former recognition unit, after performing two sequential Cu(I)-catalyzed azide-alkyne cycloadditions with a linker containing the latter recognition unit. The product, which exists as a single co-conformer, wherein the BDNP38C10 ring encircles the NpI unit, undergoes equilibration to give approximately equal amounts of the other co-conformer in which the BDNP38C10 ring encircles the BIPY2+ unit." @default.
- W2041177124 created "2016-06-24" @default.
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- W2041177124 date "2008-07-09" @default.
- W2041177124 modified "2023-10-10" @default.
- W2041177124 title "A Reverse Donor-Acceptor Bistable [2]Catenane" @default.
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- W2041177124 doi "https://doi.org/10.1021/ol800931z" @default.
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