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- W2041188226 abstract "A synthetic, structural and conformational study of 1,4,5,8-tetraazadecalin (3) and several of its new, substituted derivatives was performed. Mass-spectrometric and NMR-spectroscopic data were taken to indicate a trans-fused double chair in most cases. These findings, juxtaposed to the notorious elusiveness of trans-1,4,5,8-tetraoxadecalin (2) were rationalized in terms of a “reverse anomeric effect”. Substituent effects were also assessed: substituents in the two angular positions or on all four nitrogens preclude trans fusion in favour of the isomeric cis- and/or biimidazolidin-2-yl structures. Thecis-geometry also prevails in systems were it is imposed by bridging substituents." @default.
- W2041188226 created "2016-06-24" @default.
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- W2041188226 date "2010-09-02" @default.
- W2041188226 modified "2023-09-26" @default.
- W2041188226 title "Structure and conformation of heterocycles. X. On 1,4,5,8-tetraazadecalins" @default.
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- W2041188226 doi "https://doi.org/10.1002/recl.19790980516" @default.
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