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• W2041188552 abstract "We report on the high-pressure synthesis of ${text{BiMn}}_{7}{text{O}}_{12}$, a manganite displaying a ``quadruple-perovskite'' structure. Structural characterization of single-crystal samples shows a distorted and asymmetrical coordination around the Bi atom due to presence of the $6{text{s}}^{2}$ lone pair, resulting in noncentrosymmetric space group $Im$, leading to a permanent electrical dipole moment and ferroelectric properties. On the other hand, magnetic characterization reveals antiferromagnetic transitions in agreement with the isostructural compounds, and the dielectric constant shows anomalies matching the magnetic transition temperatures. ${text{BiMn}}_{7}{text{O}}_{12}$ is therefore a promising multiferroic material, with evidence of coupling between magnetic and dielectric properties." @default.
• W2041188552 created "2016-06-24" @default.
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• W2041188552 date "2009-03-20" @default.
• W2041188552 modified "2023-09-25" @default.
• W2041188552 title "Synthesis and characterization of multiferroic<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mtext>BiMn</mml:mtext></mml:mrow><mml:mn>7</mml:mn></mml:msub><mml:msub><mml:mtext>O</mml:mtext><mml:mrow><mml:mn>12</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>" @default.
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• W2041188552 doi "https://doi.org/10.1103/physrevb.79.100106" @default.
• W2041188552 hasPublicationYear "2009" @default.
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