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- W2041189368 abstract "Reaction of secondary 2,2,2-trifluoroethanesulfonate ester (tresylates) with tetrabutylammonium flouride (TBAF) gives methanesulfonate esters (mesylates) in yields of 60–65%. A possible mechanism for this reaction includes TBAF-induced dehydroflourination followed by hydration and hydrolysis effected by the water in TBAF (1 M in THF), and subsequently decarboxylation. This study show some limitations on the use of tresylates as leaving groups for flourine substitution in nucleophilic displacement reactions." @default.
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- W2041189368 date "1993-03-01" @default.
- W2041189368 modified "2023-09-25" @default.
- W2041189368 title "Tetrabutylammonium fluoride-induced conversion of tresylates to mesylates" @default.
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- W2041189368 doi "https://doi.org/10.1016/0040-4039(93)85011-k" @default.
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