FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2041189943> ?p ?o ?g. }

• W2041189943 endingPage "204" @default.
• W2041189943 startingPage "199" @default.
• W2041189943 abstract "A significant shortcoming of the kinetic method for determining chiral purity from the competitive dissociation of a metal complex chelated with a chiral analyte and chiral reference is that it does not give useful quantitative data for high purity chiral samples in comparison to the standard chiral chromatography techniques. To extend the range of applications of the kinetic method to high chiral purity samples, a “vernier” method is reported which gives more accurate quantitative data for samples covering a narrow range of chiral purity. This is demonstrated for the case of a model amino acid in which NiII is used as the metal cation, asparagine as the chiral reference, and the analyte is tryptophan. By selecting experimental conditions to give a measured peak abundance ratio near unity for the two competitive fragments (where abundance ratios are more accurately measured than at higher or lower values), samples of high (90–100%) chiral purity were more accurately assayed in the experiment using pure tryptophan. By switching the chirality of the reference compound, samples in the low (0–10%) chiral purity range could also be more precisely measured. The quantitative improvement in accuracy of the chiral measurement is shown by the average accuracy of 0.51% deviation (for the 90–100% chiral purity range of tryptophan using l-Asn as chiral reference) in comparison to the average deviation of 104.1% in the non-vernier region (the region that falls outside the high accuracy region of interest)." @default.
• W2041189943 created "2016-06-24" @default.
• W2041189943 creator A5036827887 @default.
• W2041189943 creator A5060777158 @default.
• W2041189943 date "2007-11-01" @default.
• W2041189943 modified "2023-09-23" @default.
• W2041189943 title "Improvements in quantitative chiral determinations using the mass spectrometric kinetic method" @default.
• W2041189943 cites W1964075015 @default.
• W2041189943 cites W1983180929 @default.
• W2041189943 cites W1984946619 @default.
• W2041189943 cites W1989130443 @default.
• W2041189943 cites W1996389527 @default.
• W2041189943 cites W1996511763 @default.
• W2041189943 cites W1998862337 @default.
• W2041189943 cites W2003410184 @default.
• W2041189943 cites W2003719997 @default.
• W2041189943 cites W2007348896 @default.
• W2041189943 cites W2008874238 @default.
• W2041189943 cites W2008949045 @default.
• W2041189943 cites W2010026236 @default.
• W2041189943 cites W2010382216 @default.
• W2041189943 cites W2010705069 @default.
• W2041189943 cites W2023654077 @default.
• W2041189943 cites W2024625137 @default.
• W2041189943 cites W2031591152 @default.
• W2041189943 cites W2034578217 @default.
• W2041189943 cites W2045417050 @default.
• W2041189943 cites W2047123369 @default.
• W2041189943 cites W2050871653 @default.
• W2041189943 cites W2054368613 @default.
• W2041189943 cites W2056171990 @default.
• W2041189943 cites W2062588416 @default.
• W2041189943 cites W2077630673 @default.
• W2041189943 cites W2078487864 @default.
• W2041189943 cites W2078995979 @default.
• W2041189943 cites W2079354839 @default.
• W2041189943 cites W2088210694 @default.
• W2041189943 cites W2089145179 @default.
• W2041189943 cites W2091795411 @default.
• W2041189943 cites W2094883618 @default.
• W2041189943 cites W2113471361 @default.
• W2041189943 cites W2146481127 @default.
• W2041189943 cites W2150267630 @default.
• W2041189943 cites W2159061024 @default.
• W2041189943 cites W2505111109 @default.
• W2041189943 cites W2949259143 @default.
• W2041189943 cites W2949359061 @default.
• W2041189943 cites W2950837477 @default.
• W2041189943 cites W2952065266 @default.
• W2041189943 cites W4230636970 @default.
• W2041189943 cites W4248199980 @default.
• W2041189943 cites W4249193895 @default.
• W2041189943 doi "https://doi.org/10.1016/j.ijms.2007.02.036" @default.
• W2041189943 hasPublicationYear "2007" @default.
• W2041189943 type Work @default.
• W2041189943 sameAs 2041189943 @default.
• W2041189943 citedByCount "28" @default.
• W2041189943 countsByYear W20411899432012 @default.
• W2041189943 countsByYear W20411899432013 @default.
• W2041189943 countsByYear W20411899432014 @default.
• W2041189943 countsByYear W20411899432015 @default.
• W2041189943 countsByYear W20411899432016 @default.
• W2041189943 countsByYear W20411899432018 @default.
• W2041189943 countsByYear W20411899432023 @default.
• W2041189943 crossrefType "journal-article" @default.
• W2041189943 hasAuthorship W2041189943A5036827887 @default.
• W2041189943 hasAuthorship W2041189943A5060777158 @default.
• W2041189943 hasConcept C10390740 @default.
• W2041189943 hasConcept C113196181 @default.
• W2041189943 hasConcept C121332964 @default.
• W2041189943 hasConcept C124668440 @default.
• W2041189943 hasConcept C135889238 @default.
• W2041189943 hasConcept C163845019 @default.
• W2041189943 hasConcept C185592680 @default.
• W2041189943 hasConcept C20621625 @default.
• W2041189943 hasConcept C43617362 @default.
• W2041189943 hasConcept C486523 @default.
• W2041189943 hasConcept C52233224 @default.
• W2041189943 hasConcept C62520636 @default.
• W2041189943 hasConcept C71240020 @default.
• W2041189943 hasConceptScore W2041189943C10390740 @default.
• W2041189943 hasConceptScore W2041189943C113196181 @default.
• W2041189943 hasConceptScore W2041189943C121332964 @default.
• W2041189943 hasConceptScore W2041189943C124668440 @default.
• W2041189943 hasConceptScore W2041189943C135889238 @default.
• W2041189943 hasConceptScore W2041189943C163845019 @default.
• W2041189943 hasConceptScore W2041189943C185592680 @default.
• W2041189943 hasConceptScore W2041189943C20621625 @default.
• W2041189943 hasConceptScore W2041189943C43617362 @default.
• W2041189943 hasConceptScore W2041189943C486523 @default.
• W2041189943 hasConceptScore W2041189943C52233224 @default.
• W2041189943 hasConceptScore W2041189943C62520636 @default.
• W2041189943 hasConceptScore W2041189943C71240020 @default.
• W2041189943 hasIssue "1-3" @default.
• W2041189943 hasLocation W20411899431 @default.
• W2041189943 hasOpenAccess W2041189943 @default.
• W2041189943 hasPrimaryLocation W20411899431 @default.
• W2041189943 hasRelatedWork W2003727193 @default.

• next