Matches in SemOpenAlex for { <https://semopenalex.org/work/W2041275220> ?p ?o ?g. }
- W2041275220 endingPage "983" @default.
- W2041275220 startingPage "975" @default.
- W2041275220 abstract "1,1,3,3-Tetramethyldisiloxane (TMDS) and polymethylhydrosiloxane (PMHS), when associated with titanium(IV) isopropoxide, provide two convenient systems for the reduction of nitriles into the corresponding primary amines. Kinetics of the two systems have been studied by 1H NMR and demonstrated that reduction with PMHS occurs faster than with TMDS. These two titanium-based systems reduce both aromatic and aliphatic nitriles in the presence of Br, CC, NO2, OH, and cyclopropyl-ring. In the case of cyclopropyl-nitriles, the formation of secondary amines, which come from an intermolecular reductive alkylation reaction was observed. This result was exploited for the reduction of dinitriles, which led, in one-step, to azepane, piperidine, pyrrolidine, and azetidine derivatives through an intramolecular reductive alkylation reaction." @default.
- W2041275220 created "2016-06-24" @default.
- W2041275220 creator A5001785925 @default.
- W2041275220 creator A5008888667 @default.
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- W2041275220 creator A5038615046 @default.
- W2041275220 creator A5041850490 @default.
- W2041275220 creator A5056850539 @default.
- W2041275220 creator A5072408618 @default.
- W2041275220 date "2014-01-01" @default.
- W2041275220 modified "2023-10-04" @default.
- W2041275220 title "Straightforward access to cyclic amines by dinitriles reduction" @default.
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