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- W2041299393 abstract "The η-M6C, γ-M23C6, and π-M11C2 phases (M = Cr, Mn and Fe) have complex cubic lattices with lattice parameters of approximately 1.0 nm. They belong to the CFCC-TmC family (complex face-centered cubic transition metal carbides), display a rich variety of crystal structures, and play in important role in iron alloys and steels. Here we show that first-principles calculations predict high stability for the γ-M23C6 and η-M6C phases, and instability for the π-M11C2 phases, taking into account various compositional and structural possibilities. The calculations also show a wide variety in magnetic properties. The Cr-containing phases were found to be non-magnetic and the Fe-phases to be ferromagnetic, while the Mn-containing phases were found to be either ferrimagnetic or non-magnetic. Details of the local atomic structures, and the formation and stability of these precipitates in alloys are discussed." @default.
- W2041299393 created "2016-06-24" @default.
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- W2041299393 date "2012-01-01" @default.
- W2041299393 modified "2023-10-16" @default.
- W2041299393 title "Stability and structures of the CFCC-TmC phases: A first-principles study" @default.
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- W2041299393 doi "https://doi.org/10.1016/j.commatsci.2011.07.017" @default.
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